Determination of the number of active sites in the metathesis reactions of 1-hexene and cyclopentene on the WC16 -Sn(CH3)4 catalytic system by an isotope method

Determination of the number of active sites in the metathesis reactions of 1-hexene and cyclopentene on the WC16 -Sn(CH3)4 catalytic system by an isotope method Full article

Journal

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230

Output data

Year: 1986, Volume: 35, Number: 12, Pages: 2573-2575 Pages count : 3 DOI: 10.1007/bf01474229

Authors

Isagulyants G.V. ¹ , Klimov A.P. ¹ , Kovalenko L.I. ¹ , Kogan V.M. ¹

Affiliations

1	N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

The percentages of primary carbene sites in the metathesis of 1-hexene and polymerization of cyclopentene on the WCl6-Sn(CH3)4 catalytic system, as indicated by a radioisotope method, are 1.3 and 1.4%, respectively, relative to starting WCl6. The Sn(CH3)4 methyl groups which participate in the formation of the starting active complexes enter the reaction products.

Isagulyants G.V. , Klimov A.P. , Kovalenko L.I. , Kogan V.M.
Determination of the number of active sites in the metathesis reactions of 1-hexene and cyclopentene on the WC16 -Sn(CH3)4 catalytic system by an isotope method
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1986. V.35. N12. P.2573-2575. DOI: 10.1007/bf01474229 OpenAlex

OpenAlex:

W2009424793

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