Catalytic systems for processes of oxidative chlorination of hydrocarbons. Communication 4. X-ray diffraction study of formation of catalysts on various classes of supports

Catalytic systems for processes of oxidative chlorination of hydrocarbons. Communication 4. X-ray diffraction study of formation of catalysts on various classes of supports Full article

Journal

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230

Output data

Year: 1986, Volume: 35, Number: 4, Pages: 696-701 Pages count : 6 DOI: 10.1007/bf00954209

Authors

Solomonik I.G. ¹ , Kurlyandskaya I.I. ¹ , Ashavskaya G.A. ¹ , Yakerson V.I. ²

Affiliations

1	N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow
2	State Scientific-Research and Design Institute of the Chlorine Industry, Moscow

1. It has been shown by means of x-ray phase analysis that in supported copper chloride catalysts for the oxidative chlorination of hydrocarbons, the salt component interacts with the support (metastable aluminum oxides or an amorphous aluminosilicate), this interaction leading to the formation of a complex multiphase system. 2. The structure of the support influences the crystallization of the excess salt component, resulting in oriented growth of the crystals. 3. On an aluminosilicate support, copper hydroxochlorides are formed selectively, so that they constitute a large part of the supported salt component.

Solomonik I.G. , Kurlyandskaya I.I. , Ashavskaya G.A. , Yakerson V.I.
Catalytic systems for processes of oxidative chlorination of hydrocarbons. Communication 4. X-ray diffraction study of formation of catalysts on various classes of supports
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1986. V.35. N4. P.696-701. DOI: 10.1007/bf00954209 OpenAlex

OpenAlex:

W215126654

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