Transformed steroids. Communication 156. Reaction of pregn-5-ene-3β,17α-diol-20-one and its 16α-methyl derivative with iodosobenzene diacetate; a one-step method for the synthesis of 17-spirooxetan-20-ones

Transformed steroids. Communication 156. Reaction of pregn-5-ene-3β,17α-diol-20-one and its 16α-methyl derivative with iodosobenzene diacetate; a one-step method for the synthesis of 17-spirooxetan-20-ones Full article

Journal

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230

Output data

Year: 1986, Volume: 35, Number: 8, Pages: 1720-1723 Pages count : 4 DOI: 10.1007/bf00954623

Authors

Turuta A.M. ¹ , Kamernitskii A.V. ¹ , Fadeeva T.M. ¹ , Zhulin A.V. ¹

Affiliations

1	N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

The main path of the reaction of 17α-hydroxypregnenolone and its 16α-methyl analog with iodosobenzene diacetate in a methanol solution of an alkali is intramolecular cyclization with the formation of 17-spiro-oxetan-20-ones.

Turuta A.M. , Kamernitskii A.V. , Fadeeva T.M. , Zhulin A.V.
Transformed steroids. Communication 156. Reaction of pregn-5-ene-3β,17α-diol-20-one and its 16α-methyl derivative with iodosobenzene diacetate; a one-step method for the synthesis of 17-spirooxetan-20-ones
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1986. V.35. N8. P.1720-1723. DOI: 10.1007/bf00954623 OpenAlex

OpenAlex:

W2313121590

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