Reaction of isoprenoid olefins with SeO2 in aprotic solvents Full article
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Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230 |
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| Output data | Year: 1986, Volume: 35, Number: 11, Pages: 2300-2306 Pages count : 7 DOI: 10.1007/bf00953345 | ||
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Abstract:
1. Previously unknown Se-organic compounds, the structure of which confirm the formation of allylseleninic acids as the primary intermediates of this reaction, were isolated in the reaction of geraniol benzyl ether and linalool and citronellol acetates with SeO2 in lowpolarity aprotic media; the products were also characterized. 2. An explanation of the results was proposed; this explanation includes conversion of the allylselenine intermediates to allylselenene intermediates, which then react intermolecularly or intermolecularly with the C=C bond to give cyclic or linear selenides.
Cite:
Grigor'eva N.Y.
, Lozanova A.V.
, Lutsenko A.I.
, Moiseenkov A.M.
Reaction of isoprenoid olefins with SeO2 in aprotic solvents
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1986. V.35. N11. P.2300-2306. DOI: 10.1007/bf00953345 OpenAlex
Reaction of isoprenoid olefins with SeO2 in aprotic solvents
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1986. V.35. N11. P.2300-2306. DOI: 10.1007/bf00953345 OpenAlex
Identifiers:
| OpenAlex: | W2319847916 |
Citing:
| DB | Citing |
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| OpenAlex | 1 |