Reaction of 1-methyluracil with phenylbenzhydrazonoyl chloride Full article
| Journal |
Chemistry of Heterocyclic Compounds
ISSN: 1573-8353 , E-ISSN: 0009-3122 |
||
|---|---|---|---|
| Output data | Year: 1986, Volume: 22, Number: 5, Pages: 532-538 Pages count : 7 DOI: 10.1007/bf00519534 | ||
| Authors |
|
||
| Affiliations |
|
Abstract:
The ambident anion of 1-methyluracil gives with phenylbenzyhydrazonoyl chloride, depending on the conditions, the N-acylation product (polar solvent, room temperature), or the O-acylation product (nonpolar solvent, heating), which rearranges to a cytosine derivative. Convenient methods have been developed for the preparation of 6-methyl-1,3-diphenyl-5,6-dihydro-5-oxopyrimido[4,3-c]triazolium chloride, a fluorescent derivative of 1-methyluracil, from the N-acylation product, and for the rapid base cleavage of the uracil ring under very mild conditions.
Cite:
Chernyshova N.B.
, Shibaev V.N.
Reaction of 1-methyluracil with phenylbenzhydrazonoyl chloride
Chemistry of Heterocyclic Compounds. 1986. V.22. N5. P.532-538. DOI: 10.1007/bf00519534 Scopus OpenAlex
Reaction of 1-methyluracil with phenylbenzhydrazonoyl chloride
Chemistry of Heterocyclic Compounds. 1986. V.22. N5. P.532-538. DOI: 10.1007/bf00519534 Scopus OpenAlex
Identifiers:
| Scopus: | 2-s2.0-34250124494 |
| OpenAlex: | W2952454263 |
Citing:
Пока нет цитирований