Terpenes in organic synthesis. Communication 1. Synthesis of (1R, 3S)-1-acetoxymethyl-3-isopropenyl-2,2-dimethylcyclobutane (sex pheromone of the grape mealybug) from verboxide

Terpenes in organic synthesis. Communication 1. Synthesis of (1R, 3S)-1-acetoxymethyl-3-isopropenyl-2,2-dimethylcyclobutane (sex pheromone of the grape mealybug) from verboxide Научная публикация

Журнал

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230

Вых. Данные

Год: 1986, Том: 35, Номер: 7, Страницы: 1453-1457 Страниц : 5 DOI: 10.1007/bf00954823

Авторы

Serebryakov E.P. ^1,2,3 , Suslova L.M. ^1,2,3 , Moiseenkov A.M. ^1,2,3 , Shavyrin S.V. ^1,2,3 , Zaikina N.V. ^1,2,3 , Sorochinskaya A.M. ^1,2,3 , Kovalev B.G. ^1,2,3

Организации

1	N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow
2	Scientific-Research and Planning Institute of Wood Chemical Industry, Gorkii
3	All-Union Scientific-Research Institute of Biological Methods of Plant Protection, Kishinev

1. (1R, 3S)-l-Acetoxymethyl-3-isopropenyl-2,2-dimethylcyclobutane, a sex attractant of the grape mealy bugPlanococcus citri (Risso), was synthesized in five steps from technical grade verboxide. 2. The overall yield of pheromone from verboxide is 2.2–2.5%, while its optical purity (43–70%) correlates with the optical purity of α-pinene converted into verboxide.

Serebryakov E.P. , Suslova L.M. , Moiseenkov A.M. , Shavyrin S.V. , Zaikina N.V. , Sorochinskaya A.M. , Kovalev B.G.
Terpenes in organic synthesis. Communication 1. Synthesis of (1R, 3S)-1-acetoxymethyl-3-isopropenyl-2,2-dimethylcyclobutane (sex pheromone of the grape mealybug) from verboxide
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1986. V.35. N7. P.1453-1457. DOI: 10.1007/bf00954823 OpenAlex

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W2088786154

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