Unexpected 20-membered macrocycles obtained by the condensation of α,α-dihalo-β-oxoaldehydes with diaminofurazan

Unexpected 20-membered macrocycles obtained by the condensation of α,α-dihalo-β-oxoaldehydes with diaminofurazan Full article

Journal

New Journal of Chemistry
ISSN: 1369-9261 , E-ISSN: 1144-0546

Output data

Year: 2024, Volume: 48, Pages: 12869-12872 Pages count : 4 DOI: 10.1039/d4nj01789g

Authors

Guseinov Firudin I. ^1,2 , Ovsyannikov Viacheslav O. ^1,2 , Shuvalova Elena V. ² , Kustov Leonid M. ² , Kobrakov Konstantin I. ^1,2 , Samigullina Aida I. ² , Mahmudov Kamran T. ^3,4,5

Affiliations

1	Kosygin State University of Russia, 117997 Moscow, Russian Federation
2	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow 119991, Russian Federation
3	Centro de Química Estrutural, Instituto Superior Técnico, Universidade de Lisboa, Av. Rovisco Pais, 1049–001 Lisboa, Portugal
4	Excellence Center, Baku State University, Z. Xalilov Str. 23, Az 1148 Baku, Azerbaijan
5	Western Caspian University, Istiqlaliyyat Str. 31, AZ 1001, Baku, Azerbaijan

Herein, we have isolated new 20-membered macrocycles by the simple condensation of α,α-dihalo-β-oxoaldehydes with diaminofurazan in acetonitrile. The interior and exterior sites of these macrocycles comprise hydrogen and halogen bond donor sites, respectively. Depending on the electron donating or accepting character of the substituents at the exterior sites of macrocyclic scaffolds, the average cavity diameters range from 8.15 to 8.47 Å.

Guseinov F.I. , Ovsyannikov V.O. , Shuvalova E.V. , Kustov L.M. , Kobrakov K.I. , Samigullina A.I. , Mahmudov K.T.
Unexpected 20-membered macrocycles obtained by the condensation of α,α-dihalo-β-oxoaldehydes with diaminofurazan
New Journal of Chemistry. 2024. V.48. P.12869-12872. DOI: 10.1039/d4nj01789g WOS Scopus OpenAlex

Web of science:	WOS:001264474200001
Scopus:	2-s2.0-85198048246
OpenAlex:	W4400215666

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OpenAlex	7
Scopus	7
Web of science	6