Organoboron compounds | Sciact

Organoboron compounds Full article

Journal

Journal of Organometallic Chemistry
ISSN: 1872-8561 , E-ISSN: 0022-328X

Output data

Year: 1984, Volume: 270, Number: 1, Pages: 17-23 Pages count : 7 DOI: 10.1016/0022-328x(84)80330-7

Authors

Gurskii M.E. ¹ , Baranin S.V. ¹ , Lutsenko A.I. ¹ , Mikhailov B.M. ¹

Affiliations

1	N.D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the U.S.S.R., Leninskii Prosp. 47, Moscow U.S.S.R.

The ate-complexes of 3,8-dimethyl-, 3,4,8-trimethyl- and 3,4,4,8-tetramethyl-3-borabicyclo[4.3.1]decane react with acetyl chloride to produce the corresponding 2-(3-methylene-5-methylcyclohex-1-yl)alkyl(dimethyl)boranes. The reaction involves the abstraction of a hydride ion from the bridgehead β-carbon atom. The organoboron compounds thus obtained were oxidized with alkaline hydrogen peroxide to the methylene-3-(2-hydroxyalkyl)-5-methylcyclohexanes.

Gurskii M.E. , Baranin S.V. , Lutsenko A.I. , Mikhailov B.M.
Organoboron compounds
Journal of Organometallic Chemistry. 1984. V.270. N1. P.17-23. DOI: 10.1016/0022-328x(84)80330-7 WOS Scopus OpenAlex

≡ Web of science:	WOS:A1984TE01200003
≡ Scopus:	2-s2.0-48549109735
≡ OpenAlex:	W1517035071