Why non-heme Mn complexes of amino 2-quinolylmethyl ligands are inactive in oxidation catalysis? An insight from X-ray data

Why non-heme Mn complexes of amino 2-quinolylmethyl ligands are inactive in oxidation catalysis? An insight from X-ray data Full article

Journal

Inorganic Chemistry Communications
ISSN: 1387-7003 , E-ISSN: 1879-0259

Output data

Year: 2023, Volume: 156, Article number : 111282, Pages count : DOI: 10.1016/j.inoche.2023.111282

Authors

Ottenbacher Roman V. ¹ , Medvedev Alexander G. ² , Nefedov Andrey A. ^3,4 , Bryliakov Konstantin P. ⁵

Affiliations

1	Boreskov Institute of Catalysis, Pr. Lavrentieva 5, Novosibirsk 630090, Russia
2	Kurnakov Institute of General and Inorganic Chemistry RAS, Leninsky Pr. 31, Moscow 119991, Russia
3	Novosibirsk State University, Pirogova 1, Novosibirsk 630090, Russia
4	Vorozhtsov Novosibirsk Institute of Organic Chemistry, Pr. Lavrentieva 9, Novosibirsk 630090, Russia
5	Zelinsky Institute of Organic Chemistry RAS, Leninsky Pr. 47, Moscow 119991, Russia

In the last decade, manganese complexes with bis-amino-bis-pyridylmethyl and structurally related N4 donor ligands have emerged as efficient catalysts of selective epoxidations and C–H oxidations of organic substrates with H2O2. Although a plethora of various ligand structures have been designed, (quinolin-2-yl)methyl moieties have not been involved in constructing such catalysts. Herewith we report crystal structures of several Mn complexes with (quinolin-2-yl)methyl and discuss possible reasons of their inactivity in oxidation catalysis.

Ottenbacher R.V. , Medvedev A.G. , Nefedov A.A. , Bryliakov K.P.
Why non-heme Mn complexes of amino 2-quinolylmethyl ligands are inactive in oxidation catalysis? An insight from X-ray data
Inorganic Chemistry Communications. 2023. V.156. 111282 . DOI: 10.1016/j.inoche.2023.111282 WOS Scopus OpenAlex

Web of science:	WOS:001071448200001
Scopus:	2-s2.0-85169014620
OpenAlex:	W4386101202

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OpenAlex	4
Scopus	4
Web of science	4