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Reaction of N-hydroxy(alkoxy)amidyl and amidoxy radicals in the sodium peroxydisulfate-copper chloride oxidizing system Научная публикация

Журнал Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230
Вых. Данные Год: 1984, Том: 33, Номер: 9, Страницы: 1887-1891 Страниц : 5 DOI: 10.1007/bf00948636
Авторы Troyanskii E.I. 1 , Svitan'ko I.V. 1 , Nikishin G.I. 1
Организации
1 N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

Реферат: 1. N,O-unsubstituted alkanehydroxamic acids R(CH2)4CONHOH (where R=H or Me) are convered in the Na2S2O8-CuCl2 oxidizing system to γ-lactones and 3-chloroalkanoic acids, respectively, by way of N-hydroxyamidyl radicals R(CH2)4CONHO and amidoxyl radicals R(CH2)4C(O)NHO. 2. In the Na2S2O8-CuCl2 oxidizing system O-methylpentanehydroxamic acid is converted to a mixture of γ- and δ-valerolactones, with a significant preponderance of γ-lactone.
Библиографическая ссылка: Troyanskii E.I. , Svitan'ko I.V. , Nikishin G.I.
Reaction of N-hydroxy(alkoxy)amidyl and amidoxy radicals in the sodium peroxydisulfate-copper chloride oxidizing system
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1984. V.33. N9. P.1887-1891. DOI: 10.1007/bf00948636 OpenAlex
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