Реферат: It is shown that using the results of quantum-mechanical calculations and the perturbation molecular orbital theory can be instrumental in predicting the rate of ion radical dimerization and the nature of the resulting products. A discussion is made of the relative dimerization rate constants for two ion radicals, for an ion radical and the parent compound, and also for a dianion and the parent compound in the case of reactions of the types “head—head”, “head—tail” and “tail—tail”. The effect of the processes leading to the formation of associates is considered.

Библиографическая ссылка: Mendkovich A.S. , Gultyai V.P.
Consideration of electrochemical dimerization reactions in terms of the perturbation molecular orbital theory
Journal of Electroanalytical Chemistry and Interfacial Electrochemistry. 1984. V.169. N1-2. P.1-7. DOI: 10.1016/0022-0728(84)80068-6 OpenAlex

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W2312978525

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