Heterogenized transition metal halides in the preparation of highly dispersed metal and metal complex catalysts. Communication 5. Liquid-phase epoxidation of cyclohexene in the presence of molybdenum pentachloride heterogenized on silica

Heterogenized transition metal halides in the preparation of highly dispersed metal and metal complex catalysts. Communication 5. Liquid-phase epoxidation of cyclohexene in the presence of molybdenum pentachloride heterogenized on silica Full article

Journal

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230

Output data

Year: 1984, Volume: 33, Number: 8, Pages: 1551-1554 Pages count : 4 DOI: 10.1007/bf00959179

Authors

Yuffa A.Ya. ^1,2 , Slinkin A.A. ^1,2 , Berentsveig V.V. ^1,2 , Kucherov A.V. ^1,2 , Ryabova V.V. ^1,2 , Stakheev A.Yu. ^1,2

Affiliations

1	M. V. Lomonosov Moscow State University, USSR
2	N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

1. The preparation was described for an effective catalyst for the epoxidation of cyclohexene by hydroperoxides consisting of molybdenum pentachloride heterogenized onto a lithium-modified silica surface. 2. The structure of the surface catalytic complexes depends on the nature of the solvent from which the deposition of MoCl5 is carried out.

Yuffa A.Y. , Slinkin A.A. , Berentsveig V.V. , Kucherov A.V. , Ryabova V.V. , Stakheev A.Y.
Heterogenized transition metal halides in the preparation of highly dispersed metal and metal complex catalysts. Communication 5. Liquid-phase epoxidation of cyclohexene in the presence of molybdenum pentachloride heterogenized on silica
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1984. V.33. N8. P.1551-1554. DOI: 10.1007/bf00959179 OpenAlex

≡ OpenAlex:

W2061491327