Direct oxidation of alkanoic acids to lactones Full article
| Journal |
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230 |
||
|---|---|---|---|
| Output data | Year: 1982, Volume: 31, Number: 10, Pages: 2041-2046 Pages count : 6 DOI: 10.1007/bf00950650 | ||
| Authors |
|
||
| Affiliations |
|
Abstract:
1. By the action of the Na2S2O8-CuCl2 system, alkanoic acids RR′CHCH(R″)CH2COOH convert into γ-lactones with high regioselectivity. 2. A reaction mechanism was proposed, including the formation from alkanoic acids of alkylcarbonyloxyl radicals, their rearrangement with 1,5-migration of the H atom into 3-carboxylalkyl radicals, and oxidative cyclization of the latter into γ-lactones.
Cite:
Troyanskii E.I.
, Svitan'ko I.V.
, Nikishin G.I.
Direct oxidation of alkanoic acids to lactones
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1982. V.31. N10. P.2041-2046. DOI: 10.1007/bf00950650 OpenAlex
Direct oxidation of alkanoic acids to lactones
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1982. V.31. N10. P.2041-2046. DOI: 10.1007/bf00950650 OpenAlex
Identifiers:
| OpenAlex: | W2950936553 |
Citing:
| DB | Citing |
|---|---|
| OpenAlex | 2 |