Synthesis of aromatic diisocyanates by carbonylation of dinitro compounds with carbon monoxide on palladium catalysts

Synthesis of aromatic diisocyanates by carbonylation of dinitro compounds with carbon monoxide on palladium catalysts Full article

Journal

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230

Output data

Year: 1980, Volume: 29, Number: 1, Pages: 117-120 Pages count : 4 DOI: 10.1007/bf00951891

Authors

Manov-Yuvenskii V.I. ^1,2 , Redoshkin B.A. ^1,2 , Nefedov B.K. ^1,2 , Belyaeva G.P. ^1,2

Affiliations

1	N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow
2	Institute of Chemistry, N. I. Lobachevskii Gor'kii State University, USSR

1. The catalytic activity of PdCl2 in the synthesis of aromatic diisocyanates by carbonylation of dinitro compounds depends on the presence of an organic base (pyridine) and a transition-metal oxide in the reaction system, and on the temperature and pressure. 2. The oxides V2O5 and MoO3 activate the PdCl2-pyridine catalyst, the oxides of Sc, Cr, Mn, and Ni reduce the yield of diisocyanates, and Co3O4, and CuO inhibit their formation. 3. The yield of aromatic diisocyanates in the presence of Pd catalysts increases with increasing CO pressure and passes through a maximum at 190–200°C.

Manov-Yuvenskii V.I. , Redoshkin B.A. , Nefedov B.K. , Belyaeva G.P.
Synthesis of aromatic diisocyanates by carbonylation of dinitro compounds with carbon monoxide on palladium catalysts
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1980. V.29. N1. P.117-120. DOI: 10.1007/bf00951891 OpenAlex

OpenAlex:

W2994915440

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