Реферат: The effect of alumina, carbon-coated alumina (CCA), and two commercial activated carbons (ACs) supports on trimetallic KCoMoS2 catalysts for ethanol conversion was studied. Supports and catalysts were characterized using high-resolution transmission electron (HRTEM) microscopy, UV spectral analysis of pyridine adsorption, scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS) and N2 physisorption to study their structural properties and morphology. The reactions were carried out under hydrogen and helium reaction atmospheres in a fixed-bed reactor. Catalysts supported on various ACs were found to be more active than those supported on γ-Al2O3 and CCA. The turnover frequency (TOF) in all the studied reactions increased both with an increase in the average length ( ) and with a decrease in dispersion (D). Product yields were higher under a helium atmosphere compared to a hydrogen atmosphere. Conversion of ethanol is supposed to occur on MoS2-based catalysts with account for the nature of the support and effects of the reaction atmosphere. The influence of catalyst acidity on product distribution and conversion was investigated; acidity was found to have no direct effect on total conversion, yet it influenced product yields.

Библиографическая ссылка: Dipheko T.D. , Maximov V.V. , Osman M.E. , Permyakov E.A. , Mozhaev A.V. , Nikulshin P.A. , Cherednichenko A.G. , Kogan V.M.
Catalytic conversion of ethanol over supported KCoMoS2 catalysts for synthesis of oxygenated hydrocarbons
Fuel. 2022. V.330. 125512 . DOI: 10.1016/j.fuel.2022.125512 WOS Scopus OpenAlex

Идентификаторы БД:

Web of science:	WOS:000860297700003
Scopus:	2-s2.0-85135867297
OpenAlex:	W4290991540

Цитирование в БД:

БД	Цитирований
OpenAlex	7
Scopus	8
Web of science	8

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