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Synthesis and nucleophilic dearomatization of highly electrophilic [1,2,5]selenadiazolo[3,4-b]pyridines Full article

Journal Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285
Output data Year: 2022, Volume: 71, Number: 8, Pages: 1826-1829 Pages count : 4 DOI: 10.1007/s11172-022-3596-x
Authors Ivanova V.V. 1 , Fedorenko A.K. 1 , Starosotnikov A.M. 1 , Bastrakov M.A. 1
Affiliations
1 N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: A number of [1,2,5]selenadiazolo[3,4-b]pyridines were synthesized on the basis of readily available 5-R-2,3-diaminopyridines. It was found that these compounds can be involved into the reactions with C-nucleophiles (1,3-dicarbonyl compounds, indoles) under mild conditions, in some cases with no base required. As a result, stable products of nucleophilic addition to the pyridine ring, 1,4-dihydropyridines fused with selenadiazole ring, were formed in up to 94% yield.
Cite: Ivanova V.V. , Fedorenko A.K. , Starosotnikov A.M. , Bastrakov M.A.
Synthesis and nucleophilic dearomatization of highly electrophilic [1,2,5]selenadiazolo[3,4-b]pyridines
Russian Chemical Bulletin. 2022. V.71. N8. P.1826-1829. DOI: 10.1007/s11172-022-3596-x WOS Scopus OpenAlex
Identifiers:
Web of science: WOS:000859732900030
Scopus: 2-s2.0-85138611959
OpenAlex: W4296885673
Citing:
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OpenAlex 9
Scopus 9
Web of science 8
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