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New azo dyes based on 8-methoxy-2,2,4-trimethyl-1,2-dihydroquinoline and N-substituted tetrazoles Full article

Journal Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285
Output data Year: 2022, Volume: 71, Number: 10, Pages: 2207-2217 Pages count : 11 DOI: 10.1007/s11172-022-3647-3
Authors Khodot E.N. 1 , Golovina G.V. 2 , Timokhina E.N. 2 , Samigullina A.I. 1 , Levina I.I. 2 , Kuzmin V.A. 2 , Nekipelova T.D. 2
Affiliations
1 N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991 Moscow, Russian Federation
2 N. M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 119334 Moscow, Russian Federation

Abstract: A new procedure for the synthesis of azo dyes based on 8-methoxy-2,2,4-trimethyl-1,2-dihydroquinoline and 1- or 2-substituted tetrazoles results in a crucial increase in the yields of the target compounds. The structures of the synthesized dyes containing Me, But, and Ad substituents at the 1 and 2 positions of the tetrazole moiety were established by NMR spectroscopy and X-ray diffraction analysis. The most stable conformations of the dyes depending on the substituent and the solvent were determined. The electronic absorption spectra in different solvents were characterized experimentally and theoretically.
Cite: Khodot E.N. , Golovina G.V. , Timokhina E.N. , Samigullina A.I. , Levina I.I. , Kuzmin V.A. , Nekipelova T.D.
New azo dyes based on 8-methoxy-2,2,4-trimethyl-1,2-dihydroquinoline and N-substituted tetrazoles
Russian Chemical Bulletin. 2022. V.71. N10. P.2207-2217. DOI: 10.1007/s11172-022-3647-3 WOS Scopus OpenAlex
Identifiers:
Web of science: WOS:000884739600021
Scopus: 2-s2.0-85141981827
OpenAlex: W4309343496
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Scopus 5
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