Synthesis, Structure, and Properties of 1,3‐Diaryl‐7‐imino‐1,7‐dihydrobenzo[e][1,2,4]triazines: Products of Unexpected Conversion of Polyfluorinated Blatter Radicals

Synthesis, Structure, and Properties of 1,3‐Diaryl‐7‐imino‐1,7‐dihydrobenzo[e][1,2,4]triazines: Products of Unexpected Conversion of Polyfluorinated Blatter Radicals Научная публикация

Журнал

European Journal of Organic Chemistry
ISSN: 1434-193X , E-ISSN: 1099-0690

Вых. Данные

Год: 2024, Том: 27, Номер: 36, Номер статьи : e202400494, Страниц : DOI: 10.1002/ejoc.202400494

Авторы

Gulyaev Dmitry ¹ , Serykh Andrey ^2,1 , Gadimov Nurlan ^2,1 , Shangin Pavel ¹ , Syroeshkin Mikhail ¹ , Sosunov Egor ^2,3 , Tretyakov Evgeny ¹

Организации

1	N.D. Zelinsky Institute of Organic Chemistry Russian Academy of Sciences (RAS) Leninsky Ave. 47 Moscow 119991 Russian Federation
2	D. Mendeleev University of Chemical Technology of Russia Miusskaya Pl. 9 Moscow 125047 Russian Federation
3	N.S. Kurnakov Institute of General and Inorganic Chemistry Leninsky Ave. 31 Moscow 119991 Russian Federation

Derivatives of the first substituted 7-imino-1,7-dihydrobenzo[e][1,2,4]triazines, namely 1-(2,3,5,6-tetrafluoropyridin-4-yl)-N,3-diphenyl-7-(phenylimino)-1,7-dihydrobenzo[e][1,2,4]triazin-6-amine and 1-(pentafluorophenyl)-N-phenyl-7-(phenylimino)-3-(2,3,4,5-tetrafluorophenyl)-1,7-dihydrobenzo[e][1,2,4]triazin-6-amine, were unexpectedly isolated as the only products in yields of about 20–30 % after an attempt to obtain Blatter radicals from the corresponding amidrazones bearing polyfluorinated electron-withdrawing substituents. All new compounds were fully characterized, and their molecular and crystal structure was determined by single-crystal X-ray diffraction.

Gulyaev D. , Serykh A. , Gadimov N. , Shangin P. , Syroeshkin M. , Sosunov E. , Tretyakov E.
Synthesis, Structure, and Properties of 1,3‐Diaryl‐7‐imino‐1,7‐dihydrobenzo[e][1,2,4]triazines: Products of Unexpected Conversion of Polyfluorinated Blatter Radicals
European Journal of Organic Chemistry. 2024. V.27. N36. e202400494 . DOI: 10.1002/ejoc.202400494 WOS OpenAlex

Web of science:	WOS:001320288400001
OpenAlex:	W4400700926

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