Visible Light Mediated Difluoroalkylation of Alkenes Using Mercaptobenzothiazole‐Derived Sulfide Reagent

Visible Light Mediated Difluoroalkylation of Alkenes Using Mercaptobenzothiazole‐Derived Sulfide Reagent Full article

Journal

Advanced Synthesis & Catalysis
ISSN: 1615-4169 , E-ISSN: 1615-4150

Output data

Year: 2024, Volume: 366, Number: 24, Pages: 5171-5175 Pages count : 5 DOI: 10.1002/adsc.202400884

Authors

Sorokin Artem ^1,2 , Levin Vitalij ¹ , Dilman Alexander D. ¹

Affiliations

1	N.D. Zelinsky Institute of Organic Chemistry, RUSSIAN FEDERATION
2	Lomonosov Moscow State University, Department of Chemistry, Moscow, 119991 Leninskie Gory 1–3, Russian Federation

A method for the reductive difluoromethylation of alkenes with 2-difluoromethylthio(benzothiazole) under photocatalytic conditions is described. The reaction involves the generation of the difluoromethyl radical by means of trimethyltriazinane, which serves as a precursor for the strongly reducing cyclic diaminoalkyl radical.

Sorokin A. , Levin V. , Dilman A.D.
Visible Light Mediated Difluoroalkylation of Alkenes Using Mercaptobenzothiazole‐Derived Sulfide Reagent
Advanced Synthesis & Catalysis. 2024. V.366. N24. P.5171-5175. DOI: 10.1002/adsc.202400884 WOS OpenAlex

Web of science:	WOS:001331294400001
OpenAlex:	W4402017401

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