Energetic Methylene‐Bridged Furoxan‐Triazole/Tetrazole Hybrids

Energetic Methylene‐Bridged Furoxan‐Triazole/Tetrazole Hybrids Full article

Journal

ChemPlusChem
ISSN: 1212-6950 , E-ISSN: 0010-0765

Output data

Year: 2024, Volume: 89, Number: 12, Article number : e202400496, Pages count : DOI: 10.1002/cplu.202400496

Authors

Shaferov Alexander ¹ , Ananyev Ivan ^2,3 , Monogarov Konstantin ⁴ , Fomenkov Igor ¹ , Pivkina Alla ⁴ , Fershtat Leonid ^1,5

Affiliations

1	Zelinsky Institute of Organic Chemistry RAS, Laboratory of Nitrogen Compounds, RUSSIAN FEDERATION
2	A N Nesmeyanov Institute of Organoelement Compounds RAS, Laboratory of Quantum Chemistry, RUSSIAN FEDERATION
3	N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, GSP-1, Leninsky prosp., 31, 119991 Moscow, Russian Federation
4	FSBIS N N Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences Chernogolovka Branch, Laboratory of Energetic Materials, RUSSIAN FEDERATION
5	National Research University Higher School of Economics, 101000 Myasnitskaya str., 20, Moscow, Russian Federation

Design and synthesis of new energetic materials retains its urgency in chemistry and materials science. Herein, rational construction and regioselective synthesis of a series of energetic compounds comprising of a methylene-bridged combination of 1,2,5-oxadiazole and nitrogen-rich azoles (1,2,4-triazole and tetrazole) enriched with additional explosophoric functionalities (nitro and azo moieties) is presented. All target materials were thoroughly characterized using IR and multinuclear NMR (1H, 13C, 14N, 15N) NMR spectroscopy, high-resolution mass spectrometry, X-ray diffraction, and differential scanning calorimetry. All synthesized energetic substances showed good thermal stability (up to 239 °C) and low mechanical sensitivity, while their performance reached or exceeded the level of TNT.

Shaferov A. , Ananyev I. , Monogarov K. , Fomenkov I. , Pivkina A. , Fershtat L.
Energetic Methylene‐Bridged Furoxan‐Triazole/Tetrazole Hybrids
ChemPlusChem. 2024. V.89. N12. e202400496 . DOI: 10.1002/cplu.202400496 OpenAlex

OpenAlex:

W4402071704

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