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Characteristics and Magnetic Properties of Carbon-Coated Cobalt Nanoparticles Deposited on Silica Научная публикация

Журнал Russian Journal of Physical Chemistry A
ISSN: 0036-0244 , E-ISSN: 1531-863X
Вых. Данные Год: 2024, Том: 98, Номер: 12, Страницы: 2792-2797 Страниц : 6 DOI: 10.1134/s0036024424702030
Авторы Chernavskii P.A. 1,4 , Maksimov S.V. 1 , Pankina G.V. 1 , Novotortsev R.Yu. 1 , Shumiytsev A.V. 2 , Panfilov S.I. 3 , Novakova A.A. 3 , Eliseev O.L. 4
Организации
1 Faculty of Chemistry, Moscow State University, 119991, Moscow, Russia
2 All-Russian Institute for Scientific and Technical Information (VINITI), 125315, Moscow, Russia
3 Faculty of Physics, Moscow State University, 119991, Moscow, Russia
4 Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

Реферат: Cobalt nanoparticles embedded in a carbon matrix were obtained by thermolysis of glucose deposited on Co3O4/SiO2. The magnetic characteristics of the obtained nanoparticles were measured. This process formed single-domain (d < 20 nm) carbon-coated Co nanoparticles. The average size and the size distribution of Co nanoparticles depend on the amount of glucose used for the preparation. The use of a relatively small amount of glucose (glucose/cobalt < 1 mol/mol) leads to the formation of carbon shells enveloping Co nanoparticles, which are resistant to oxidation in air up to 200°C. In contrast, the use of a larger amount of glucose leads to the formation of an amorphous carbon layer with metal particles enclosed in it. Thus, the resulting nanoparticles are more susceptible to oxidation, and approximately half of the deposited cobalt is oxidized to CoO within a few days of exposure to air.
Библиографическая ссылка: Chernavskii P.A. , Maksimov S.V. , Pankina G.V. , Novotortsev R.Y. , Shumiytsev A.V. , Panfilov S.I. , Novakova A.A. , Eliseev O.L.
Characteristics and Magnetic Properties of Carbon-Coated Cobalt Nanoparticles Deposited on Silica
Russian Journal of Physical Chemistry A. 2024. V.98. N12. P.2792-2797. DOI: 10.1134/s0036024424702030 WOS Scopus OpenAlex
Идентификаторы БД:
Web of science: WOS:001359202500006
Scopus: 2-s2.0-85209580767
OpenAlex: W4404469507
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