Magnetism of Manganese Complexes with Fluorinated Benzimidazole-Substituted Nitronyl Nitroxides

Magnetism of Manganese Complexes with Fluorinated Benzimidazole-Substituted Nitronyl Nitroxides Научная публикация

Журнал

Inorganics (Basel)
ISSN: 2304-6740

Вых. Данные

Год: 2024, Том: 12, Номер: 12, Номер статьи : 323, Страниц : DOI: 10.3390/inorganics12120323

Авторы

Tretyakov Evgeny ¹ , Bakuleva Nadejda ¹ , Efimov Nikolay ² , Kulikova Elizaveta ³ , Luneau Dominique ⁴

Организации

1	N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Prospekt 47, Moscow 119991, Russia
2	N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninsky Prospekt 31, Moscow 119991, Russia
3	NRC Kurchatov Institute, Akademika Kurchatova Pl. 1, Moscow 123182, Russia
4	Laboratoire des Multimatériaux et Interfaces (UMR 5615), Université Claude Bernard Lyon-1, Campus de La Doua, 69622 Villeurbanne Cedex, France

A series of layered compounds of the formula {[Mn2(radical)3](ClO4)}n was obtained by a reaction (in methanol) of manganese(II) acetate with 2-(2-benzimidazolyl)-4,4,5,5-tetramethylimidazolidinyl-1-oxy-3-oxides fluorinated on the benzene ring and by successive addition of sodium perchlorate. This study showed that the magnetic properties of the complexes are sensitive to the number and arrangement of fluorine atoms in the paramagnetic ligands. It was found that the heterospin complex with 4-FBzIm-NN behaves as a magnet with Curie temperature TC = 50 K, which is close to that of the {[Mn2(BzIm-NN)3](ClO4)}n complex containing a nonfluorinated ligand. Meanwhile, no 3D ordering was noted for complexes with difluorinated and 5-fluoro-substituted ligands.

Tretyakov E. , Bakuleva N. , Efimov N. , Kulikova E. , Luneau D.
Magnetism of Manganese Complexes with Fluorinated Benzimidazole-Substituted Nitronyl Nitroxides
Inorganics (Basel). 2024. V.12. N12. 323 . DOI: 10.3390/inorganics12120323 WOS OpenAlex

Web of science:	WOS:001384800600001
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