Transformed steroids. 92. Synthesis and reactions of steroidal 16→23-Lactones Full article
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Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230 |
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| Output data | Year: 1978, Volume: 27, Number: 1, Pages: 164-167 Pages count : 4 DOI: 10.1007/bf01153232 | ||
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Abstract:
1. We have synthesized steroidal 16→23-dihydroxylactones structurally related to chiograsterins, by trans-opening of the ethyl ester of 16α,17α-oxido-24-norchol-5-ene-3,20-diol-23-oic acid 3-acetate. 2. Degradation of the 17α,20ξ-dihydroxy-23→16-lactone gives the 17-acetoxy-Δ20(22)-23→ 16 lactone, epoxidation of which forms the 23→16(δ)- and 23→17(γ)-lactones of the steroid series.
Cite:
Kamernitskii A.V.
, Krivoruchko V.A.
, Reshetova I.G.
Transformed steroids. 92. Synthesis and reactions of steroidal 16→23-Lactones
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1978. V.27. N1. P.164-167. DOI: 10.1007/bf01153232 OpenAlex
Transformed steroids. 92. Synthesis and reactions of steroidal 16→23-Lactones
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1978. V.27. N1. P.164-167. DOI: 10.1007/bf01153232 OpenAlex
Identifiers:
| OpenAlex: | W2951032101 |
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