Asymmetric synthesis in the 1,4-addition of cyclopentadiene to (-)-menthyl methacrylate

Asymmetric synthesis in the 1,4-addition of cyclopentadiene to (-)-menthyl methacrylate Full article

Journal

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230

Output data

Year: 1978, Volume: 27, Number: 4, Pages: 764-766 Pages count : 3 DOI: 10.1007/bf00925302

Authors

Mamedov E.G. ^1,2 , Akhmedov I.M. ^1,2 , Guseinov M.M. ^1,2 , Piloyan S.R. ^1,2 , Klabunovskii E.I. ^1,2

Affiliations

1	Institute of Petrochemical Processes, Sumgait Branch of the Academy of Sciences of the Azerbaidzhan SSR, USSR
2	N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

1. We have carried out an asymmetric synthesis of norbornene derivatives by reaction of cyclopentadiene with menthyl methacrylate; at higher temperatures the overall yield of the adduct and the proportion of the exo isomer are much greater, while the optical yield increases slightly. 2. We have calculated the boiling points and Kovats retention indices of the synthetic compounds from the Chromatographie parameters.

Mamedov E.G. , Akhmedov I.M. , Guseinov M.M. , Piloyan S.R. , Klabunovskii E.I.
Asymmetric synthesis in the 1,4-addition of cyclopentadiene to (-)-menthyl methacrylate
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1978. V.27. N4. P.764-766. DOI: 10.1007/bf00925302 OpenAlex

OpenAlex:

W2951326367

DB	Citing
OpenAlex	1