Functional sulfur-containing compounds 2. Synthesis of 3-chloropropyl and 4-chlorobutyl alkyl (phenyl) sulfones by the oxidative chlorination of 3-hydroxypropyl and 4-hydroxybutyl alkyl(phenyl) sulfides and sulfoxides

Functional sulfur-containing compounds 2. Synthesis of 3-chloropropyl and 4-chlorobutyl alkyl (phenyl) sulfones by the oxidative chlorination of 3-hydroxypropyl and 4-hydroxybutyl alkyl(phenyl) sulfides and sulfoxides Full article

Journal

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230

Output data

Year: 1978, Volume: 27, Number: 9, Pages: 1823-1829 Pages count : 7 DOI: 10.1007/bf00929230

Authors

Derzhinskii A.R. ¹ , Konyushkin L.D. ¹ , Prilezhaeva E.N. ¹

Affiliations

1	N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

1. 3-Chloropropyl and 4-chlorobutyl alkyl (phenyl) sulfones have been obtained with high yields as a result of the oxidative chlorination of 3-hydroxypropyl and 4-hydroxybutyl alkyl (phenyl) sulfides. In the presence of FeCl3 (and other salts of metals) the oxidative chlorination can be stopped at the formation of the corresponding sulfoxides. 2. The OH group of the original compound is directly involved in the formation of the sulfonyl group. A possible mechanism for the oxidative chlorination of hydroxyalkyl sulfides and sulfoxides has been considered.

Derzhinskii A.R. , Konyushkin L.D. , Prilezhaeva E.N.
Functional sulfur-containing compounds 2. Synthesis of 3-chloropropyl and 4-chlorobutyl alkyl (phenyl) sulfones by the oxidative chlorination of 3-hydroxypropyl and 4-hydroxybutyl alkyl(phenyl) sulfides and sulfoxides
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1978. V.27. N9. P.1823-1829. DOI: 10.1007/bf00929230 OpenAlex

≡ OpenAlex:

W2951790309