Free-radical reaction of tetrachloroethylene with methanol Full article
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Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230 |
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| Output data | Year: 1978, Volume: 27, Number: 1, Pages: 139-142 Pages count : 4 DOI: 10.1007/bf01153226 | ||
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Abstract:
1. The reaction of tetrachloroethylene with methanol initiated by di-t-butyl peroxide forms trichloroallyl alcohol, which inhibits this process. The inhibitory effect increases with the concentration of trichloroallyl alcohol. 2. Inhibition results mainly from two radical reactions involving trichloroallyl alcohol; abstraction of a hydrogen atom from the methylene group and addition of a hydroxymethyl radical to the double bond of the alcohol.
Cite:
Nikishin G.I.
, Vol'kenshtein Y.B.
, Salamandra L.K.
, Botnikov M.Y.
, Yakovlev I.P.
, Lubuzh E.D.
Free-radical reaction of tetrachloroethylene with methanol
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1978. V.27. N1. P.139-142. DOI: 10.1007/bf01153226 OpenAlex
Free-radical reaction of tetrachloroethylene with methanol
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1978. V.27. N1. P.139-142. DOI: 10.1007/bf01153226 OpenAlex
Identifiers:
| OpenAlex: | W2952963569 |
Citing:
| DB | Citing |
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| OpenAlex | 1 |