Reaction of 6-nitro-2, 9-dioxa-1-azabicyclo[4.3.0]nonane derivatives with nucleophiles

Reaction of 6-nitro-2, 9-dioxa-1-azabicyclo[4.3.0]nonane derivatives with nucleophiles Full article

Journal

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230

Output data

Year: 1978, Volume: 27, Number: 11, Pages: 2371-2373 Pages count : 3 DOI: 10.1007/bf00946705

Authors

Chlenov I.E. ¹ , Pal'tseva G.D. ¹ , Petrova I.M. ¹ , Shitkin V.M. ¹ , Tartakovskii V.A. ¹

Affiliations

1	N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

1. In 6-nitro-2,9-dioxa-1-azabicyclo[4.3.0]nonane derivatives when reacted with sodium azide in aqueous acetone the nitro group is replaced by the azido group. 2. The reaction of 6-nitro-8-phenyl-2, 9-dioxa-1-azabicyclo[4.3.0]nonane with diethylamine in abs. THF, or with the K salt of nitroethane in aqueous DMF, leads to replacement of the nitro group by hydroxyl. 3. 3-(γ-Hydroxypropyl)-5-phenylisoxazoline is formed when 6-nitro-8-phenyl-2,9-dioxa-1-azabicyclo[4.3.0]nonane is reacted with NaHS.

Chlenov I.E. , Pal'tseva G.D. , Petrova I.M. , Shitkin V.M. , Tartakovskii V.A.
Reaction of 6-nitro-2, 9-dioxa-1-azabicyclo[4.3.0]nonane derivatives with nucleophiles
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1978. V.27. N11. P.2371-2373. DOI: 10.1007/bf00946705 OpenAlex

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