Catalytic synthesis of aromatic monoisocyanates from nitro compounds and carbon monoxide Научная публикация
Журнал |
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230 |
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Вых. Данные | Год: 1978, Том: 27, Номер: 10, Страницы: 2066-2069 Страниц : 4 DOI: 10.1007/bf00946528 | ||
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Реферат:
1. We have synthesized aromatic monoisocyanates in 78–90% yield by carbonylation of nitro compounds with carbon monoxide in the presence of a PdCl2 + pyridine + V2O5, V2O4, or MoO3 catalyst at 200°C and a CO pressure of 50–100 atm. 2. The reactivity of methyl- and chlorine-substituted nitrobenzenes depends only slightly on the number and position of the substituents in the phenyl ring. 3. The reactivity of halogen-substituted nitrobenzenes diminishes in the order Cl > Br ≫ I.
Библиографическая ссылка:
Nefedov B.K.
, Manov-Yuvenskii V.I.
Catalytic synthesis of aromatic monoisocyanates from nitro compounds and carbon monoxide
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1978. V.27. N10. P.2066-2069. DOI: 10.1007/bf00946528 OpenAlex
Catalytic synthesis of aromatic monoisocyanates from nitro compounds and carbon monoxide
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1978. V.27. N10. P.2066-2069. DOI: 10.1007/bf00946528 OpenAlex
Идентификаторы БД:
OpenAlex: | W2995926652 |
Цитирование в БД:
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OpenAlex | 1 |