Straightforward method for the synthesis of 2H‐furo[3,2‐b]pyran‐2‐one derivatives starting from allomaltol

Straightforward method for the synthesis of 2H‐furo[3,2‐b]pyran‐2‐one derivatives starting from allomaltol Научная публикация

Журнал

Journal of Heterocyclic Chemistry
ISSN: 0022-152X , E-ISSN: 1943-5193

Вых. Данные

Год: 2024, Том: 61, Номер: 1, Страницы: 86-92 Страниц : 7 DOI: 10.1002/jhet.4744

Авторы

Komogortsev Andrey N. ¹ , Lichitsky Boris V. ¹ , Milyutin Constantine V. ¹ , Melekhina Valeriya G. ¹

Организации

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Science, Moscow, Russia

We developed a facile approach for the preparation of a rare 2H-furo[3,2-b]pyran-2-one system. The suggested method is based on a two-step process using unsubstituted allomaltol as a starting compound. The key stage of the considered route is a condensation of 2-(2-aryl-2-oxoethyl)-3-hydroxy-6-methyl-4H-pyran-4-ones with 1,1-carbonyldiimidazole. The advantages of the presented method are commercially available starting materials and convenient experimental procedures including simple isolation of the target compounds. The structure of one of the 2H-furo[3,2-b]pyran-2-ones was confirmed by x-ray diffraction

Komogortsev A.N. , Lichitsky B.V. , Milyutin C.V. , Melekhina V.G.
Straightforward method for the synthesis of 2H‐furo[3,2‐b]pyran‐2‐one derivatives starting from allomaltol
Journal of Heterocyclic Chemistry. 2024. V.61. N1. P.86-92. DOI: 10.1002/jhet.4744 WOS Scopus OpenAlex

Web of science:	WOS:001086359900001
Scopus:	2-s2.0-85174286578
OpenAlex:	W4387777957

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