4,4′-(Butane-1,4-diyl)bis(4-methyl-1,2-dioxolane-3,5-dione)

4,4′-(Butane-1,4-diyl)bis(4-methyl-1,2-dioxolane-3,5-dione) Full article

Journal

Molbank
ISSN: 1422-8599

Output data

Year: 2022, Volume: 2022, Number: 4, Article number : M1497, Pages count : DOI: 10.3390/m1497

Authors

Vil’ Vera A. ¹ , Gorlov Evgenii S. ¹ , Terent’ev Alexander O. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Prospect, 119991 Moscow, Russia

Over the past decades, studies of cyclic diacyl peroxides have shown superior or even fundamentally new reactivity compared to their acyclic counterparts in various reactions. Previously, the scope of cyclic diacyl peroxides was limited to the mono peroxy compounds. The first doubled cyclic diacyl peroxide is presented herein. The diperoxide was characterized by NMR spectroscopy, mass spectrometry, and IR spectroscopy. The structure of 4,4′-(butane-1,4-diyl)bis(4-methyl-1,2-dioxolane-3,5-dione) was confirmed by X-ray diffraction analysis. The novel diperoxide was prepared in a 55% overall yield in three steps from dibromobutane and diethyl methylmalonate.

Vil’ V.A. , Gorlov E.S. , Terent’ev A.O.
4,4′-(Butane-1,4-diyl)bis(4-methyl-1,2-dioxolane-3,5-dione)
Molbank. 2022. V.2022. N4. M1497 . DOI: 10.3390/m1497 WOS Scopus OpenAlex

Web of science:	WOS:000904250400001
Scopus:	2-s2.0-85144676691
OpenAlex:	W4309287251

DB	Citing
OpenAlex	2
Scopus	2
Web of science	1