Acylation of norcarane and its derivatives by pivaloyl tetrafluoroborate

Acylation of norcarane and its derivatives by pivaloyl tetrafluoroborate Full article

Journal

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230

Output data

Year: 1976, Volume: 25, Number: 11, Pages: 2338-2344 Pages count : 7 DOI: 10.1007/bf00973391

Authors

Tomilov Yu.V. ¹ , Smit V.A. ¹ , Nefedov O.M. ¹

Affiliations

1	N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

The decomposition of the complex obtained in the reaction of pivaloyl tetrafluoroborate with norcarane and its 1-methyl and 1-phenyl derivatives by water gives 1-hydroxy-3-pivaloyl derivatives of cyclohexanes and the corresponding unsaturated ketones. The hydride decomposition of the same complex leads to derivatives of 6-oxabicyclo[3.2.1]octane.

Tomilov Y.V. , Smit V.A. , Nefedov O.M.
Acylation of norcarane and its derivatives by pivaloyl tetrafluoroborate
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1976. V.25. N11. P.2338-2344. DOI: 10.1007/bf00973391 OpenAlex

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