Synthesis of 2-chloroethyl alkyl sulfones by the oxidative chlorination of 2-hydroxyethyl alkyl sulfides

Synthesis of 2-chloroethyl alkyl sulfones by the oxidative chlorination of 2-hydroxyethyl alkyl sulfides Full article

Journal

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230

Output data

Year: 1976, Volume: 25, Number: 4, Pages: 919-921 Pages count : 3 DOI: 10.1007/bf00922417

Authors

Derzhinskii A.R. ¹ , Konyushkin L.D. ¹ , Vershinin P.V. ¹ , Varshaver E.V. ¹ , Mokrushin M.V. ¹ , Prilezhaeva E.N. ¹

Affiliations

1	N. D. Zelinskii Institute of Organic Chemistry of the Academy of Sciences of the USSR, Moscow

1. The corresponding 2-chloroethyl alkyl(phenyl) sulfones were obtained in high yield by oxidizing the 2-hydroxyethyl alkyl(phenyl) sulfides with chlorine in water; the dehydrohalogenation of the former in the presence of bases yields the corresponding vinyl sulfones. 2. The generality of the oxidative chlorination for 2-hydroxyethyl alkyl(phenyl) sulfides, which have no branching in the α-position to the sulfur atom, was demonstrated.

Derzhinskii A.R. , Konyushkin L.D. , Vershinin P.V. , Varshaver E.V. , Mokrushin M.V. , Prilezhaeva E.N.
Synthesis of 2-chloroethyl alkyl sulfones by the oxidative chlorination of 2-hydroxyethyl alkyl sulfides
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1976. V.25. N4. P.919-921. DOI: 10.1007/bf00922417 OpenAlex

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