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Influence of the Promoter Deposition Conditions on the Catalytic Properties of Ruthenium–Cobalt Systems in the Fischer–Tropsch Synthesis Научная публикация

Журнал Petroleum Chemistry
ISSN: 0965-5441 , E-ISSN: 1555-6239
Вых. Данные Год: 2022, Том: 62, Номер: 11, Страницы: 1308-1314 Страниц : 7 DOI: 10.1134/s0965544122100115
Авторы Mazurova K.M. 1 , Miyassarova A.F. 1 , Kazantsev R.V. 2 , Eliseev O.L. 2 , Stavitskaya A.V. 1
Организации
1 Gubkin Russia State University of Oil and Gas (National Research University)
2 Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia

Реферат: The composition, structure, catalytic activity, and selectivity of alumina-supported cobalt catalysts promoted with ruthenium deposited by different methods were studied. The systems with bimetallic RuCo nanoparticles were studied in the Fischer–Tropsch synthesis. The catalyst containing 13.38 wt % Co and 0.11 wt % Ru, prepared by microwave-assisted promoter deposition, exhibits higher selectivity with respect to liquid products (yield of С5+ hydrocarbons 82.1%) and higher chain growth factor (α = 0.863) compared to the systems of similar composition (13.51 wt % Co, 0.13 wt % Ru), prepared using ultrasonic treatment. Microwave irradiation leads to the homogeneous distribution of bimetallic particles on the inner and outer surfaces of support pores, which results in increased yield of high-molecular-mass products in the Fischer–Tropsch process.
Библиографическая ссылка: Mazurova K.M. , Miyassarova A.F. , Kazantsev R.V. , Eliseev O.L. , Stavitskaya A.V.
Influence of the Promoter Deposition Conditions on the Catalytic Properties of Ruthenium–Cobalt Systems in the Fischer–Tropsch Synthesis
Petroleum Chemistry. 2022. V.62. N11. P.1308-1314. DOI: 10.1134/s0965544122100115 WOS Scopus OpenAlex
Идентификаторы БД:
Web of science: WOS:000901852400003
Scopus: 2-s2.0-85144502414
OpenAlex: W4313468893
Цитирование в БД:
БД Цитирований
OpenAlex 5
Scopus 5
Web of science 5
Альметрики: