Regioselective Baeyer–Villiger Oxidation of Steroidal Ketones to Lactones Using BF3/H2O2

Regioselective Baeyer–Villiger Oxidation of Steroidal Ketones to Lactones Using BF3/H2O2 Full article

Journal

European Journal of Organic Chemistry
ISSN: 1434-193X , E-ISSN: 1099-0690

Output data

Year: 2020, Volume: 2020, Number: 3, Pages: 402-405 Pages count : 4 DOI: 10.1002/ejoc.201901701

Authors

Ilovaisky Alexey I. ^1,2 , Merkulova Valentina M. ² , Vil Vera A. ^1,2 , Chernoburova Elena I. ² , Shchetinina Marina A. ² , Loguzov Sergey D. ² , Dmitrenok Andrey S. ² , Zavarzin Igor V. ² , Terent'ev Alexander O. ^1,3,2

Affiliations

1	All-Russian Research Institute for Phytopathology, 143050 Moscow, Russian Federation
2	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Prospect, 119991 Moscow, Russian Federation
3	D.I. Mendeleev University of Chemical Technology of Russia, 125047 Moscow, Russian Federation

A regioselective Baeyer–Villiger oxidation of estrone and androstane derivatives into 17a-oxa-D-homosteroids was developed. An important feature of this reaction lies in the selective formation of oxidation products in moderate to high yields using BF3·Et2O/ H2O2 system traditionally applied for peroxide synthesis.

Ilovaisky A.I. , Merkulova V.M. , Vil V.A. , Chernoburova E.I. , Shchetinina M.A. , Loguzov S.D. , Dmitrenok A.S. , Zavarzin I.V. , Terent'ev A.O.
Regioselective Baeyer–Villiger Oxidation of Steroidal Ketones to Lactones Using BF3/H2O2
European Journal of Organic Chemistry. 2020. V.2020. N3. P.402-405. DOI: 10.1002/ejoc.201901701 WOS Scopus OpenAlex

Web of science:	WOS:000505989800001
Scopus:	2-s2.0-85077867756
OpenAlex:	W2998986733

DB	Citing
OpenAlex	12
Scopus	14
Web of science	11