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Overclocking Nitronyl Nitroxide Gold Derivatives in Cross‐Coupling Reactions Научная публикация

Журнал Chemistry: A European Journal
ISSN: 0947-6539 , E-ISSN: 1521-3765
Вых. Данные Год: 2023, Том: 29, Номер: 6, Номер статьи : e202203118, Страниц : DOI: 10.1002/chem.202203118
Авторы Zayakin Igor 1 , Tretyakov Evgeny 1 , Akyeva Anna 1 , Syroeshkin Mikhail 1 , Burykina Julia 1 , Dmitrenok Andrey 1 , Korlyukov Alexander 2 , Nasyrova Darina 1 , Bagryanskaya Irina 3 , Stass Dmitri 4 , Ananikov Valentine 1
Организации
1 N. D. Zelinsky Institute of Organic Chemistry 47 Leninsky Prosp., 119991 Moscow (Russia)
2 A. N. Nesmeyanov Institute of Organoelement Compounds 28 Vavilov Str., 119991 Moscow (Russia)
3 N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry 9 Akad. Lavrentyev Prosp., 630090 Novosibirsk (Russia)
4 V. V. Voevodsky Institute of Chemical Kinetics and Combustion 3 Institutskaya Str., 630090 Novosibirsk (Russia)

Реферат: Nitronyl nitroxides are functional building blocks in cutting-edge research fields, such as the design of molecular magnets, the development of redox and photoswitchable molecular systems and the creation of redox-active components for organic and hybrid batteries. The key importance of the nitronyl nitroxide function is to translate molecular-level-optimized structures into nano-scale devices and new technologies. In spite of great importance, efficient and versatile synthetic approaches to these compounds still represent a challenge. Particularly, methods for the direct introduction of a nitronyl nitroxide moiety into aromatic systems possess many limitations. Here, we report gold derivatives of nitronyl nitroxide that can enter Pd(0)-catalysed cross-coupling reactions with various aryl bromides, affording the corresponding functionalized nitronyl nitroxides. Based on the high thermal stability and enhanced reactivity in catalytic transformation, a new reagent is suggested for the synthesis of radical systems via a universal cross-coupling approach.
Библиографическая ссылка: Zayakin I. , Tretyakov E. , Akyeva A. , Syroeshkin M. , Burykina J. , Dmitrenok A. , Korlyukov A. , Nasyrova D. , Bagryanskaya I. , Stass D. , Ananikov V.
Overclocking Nitronyl Nitroxide Gold Derivatives in Cross‐Coupling Reactions
Chemistry: A European Journal. 2023. V.29. N6. e202203118 . DOI: 10.1002/chem.202203118 WOS Scopus OpenAlex
Идентификаторы БД:
Web of science: WOS:000893567300001
Scopus: 2-s2.0-85143277362
OpenAlex: W4306777642
Цитирование в БД:
БД Цитирований
OpenAlex 11
Scopus 9
Web of science 6
Альметрики: