Synthesis of New Hybrid Molecules Based on Isomerically Pure 5Z,9Z-Alkadienoic Acids and Monocarbonyl Curcumin Analog

Synthesis of New Hybrid Molecules Based on Isomerically Pure 5Z,9Z-Alkadienoic Acids and Monocarbonyl Curcumin Analog Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1608-3393 , E-ISSN: 1070-4280

Output data

Year: 2022, Volume: 58, Number: 12, Pages: 1963-1968 Pages count : 6 DOI: 10.1134/s1070428022120272

Authors

Islamov I.I. ¹ , Yusupova A.V. ¹ , D’yakonov V.A. ² , Dzhemilev U.M. ²

Affiliations

1	Institute of Petrochemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences, Ufa, 450075 Russia
2	Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 119991 Russia

Previously unknown hybrid compounds based on monocarbonyl curcumin analog and long-chain (5Z,9Z)-alka-5,9-dienoic acids were synthesized for the first time in 61–67% yields. The required unsaturated acids were prepared via Cp2TiCl2-catalyzed stereoselective intermolecular cross-cyclomagnesiation of aliphatic 1,2-dienes and 2-(hepta-5,6-dien-1-yloxy)tetrahydro-2H-pyran as the key step.

Islamov I.I. , Yusupova A.V. , D’yakonov V.A. , Dzhemilev U.M.
Synthesis of New Hybrid Molecules Based on Isomerically Pure 5Z,9Z-Alkadienoic Acids and Monocarbonyl Curcumin Analog
Russian Journal of Organic Chemistry. 2022. V.58. N12. P.1963-1968. DOI: 10.1134/s1070428022120272 WOS Scopus OpenAlex

Web of science:	WOS:000933777000027
Scopus:	2-s2.0-85147749610
OpenAlex:	W4319598866

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