Synthesis and some reactions of sulfides of the thiophene series XVI. The direction of the dealkylation of α,β-bis(alkylthio)thiophenes with sodium in liquid ammonia

Synthesis and some reactions of sulfides of the thiophene series XVI. The direction of the dealkylation of α,β-bis(alkylthio)thiophenes with sodium in liquid ammonia Full article

Journal

Chemistry of Heterocyclic Compounds
ISSN: 1573-8353 , E-ISSN: 0009-3122

Output data

Year: 1971, Volume: 4, Number: 5, Pages: 574-578 Pages count : 5 DOI: 10.1007/bf00481019

Authors

Bogdanov V.S. ¹ , Kalik M.A. ¹ , Kessenikh A.V. ¹ , Gol'dfarb Ya.L. ¹

Affiliations

1	Zelinskii Institute of Organic Chemistry AS USSR, Moscow

The action of two equivalents of sodium in liquid ammonia on bis(alkylthio)thiophenes of types Ia and b leads to the splitting off of the alkyl group from the sulfur atom in the α-position of the thiophene ring and the formation of the corresponding α-mercaptothiophenes II and III. The PMR spectra of the compounds obtained are given.

Bogdanov V.S. , Kalik M.A. , Kessenikh A.V. , Gol'dfarb Y.L.
Synthesis and some reactions of sulfides of the thiophene series XVI. The direction of the dealkylation of α,β-bis(alkylthio)thiophenes with sodium in liquid ammonia
Chemistry of Heterocyclic Compounds. 1971. V.4. N5. P.574-578. DOI: 10.1007/bf00481019 OpenAlex

OpenAlex:

W3159519810

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