Polarographic study of aliphatic nitro compounds. Communication 5. Mechanism of the electrochemical reduction of certain fluoropolynitroalkanes

Polarographic study of aliphatic nitro compounds. Communication 5. Mechanism of the electrochemical reduction of certain fluoropolynitroalkanes Full article

Journal

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230

Output data

Year: 1971, Volume: 20, Number: 8, Pages: 1586-1589 Pages count : 4 DOI: 10.1007/bf00860008

Authors

Petrosyan V.A. ¹ , Mairanovskii S.G. ¹ , Okhlobystina L.V. ¹ , Slovetskii V.I. ¹ , Fainzil'berg A.A. ¹

Affiliations

1	N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

1. The reduction of fluorotrinitromethane, fluorodinitromethane, and 1-fluoro-1,1-dinitroethane was studied on a dropping mercury electrode. 2. The first step in the electrochemical reduction of fluorotrinitromethane and fluorodinitromethane is stripping of a nitro group. 3. On the polarograms of fluorodinitromethane there are waves corresponding to the reduction of its nonionized form and the anion, and the first step in the reduction of the fluorodinitromethyl anion is a one-electron process, leading to the formation of a dianion radical of fluorodinitromethane.

Petrosyan V.A. , Mairanovskii S.G. , Okhlobystina L.V. , Slovetskii V.I. , Fainzil'berg A.A.
Polarographic study of aliphatic nitro compounds. Communication 5. Mechanism of the electrochemical reduction of certain fluoropolynitroalkanes
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1971. V.20. N8. P.1586-1589. DOI: 10.1007/bf00860008 OpenAlex

OpenAlex:

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