O- and C-methylation of some 2-acetyl-1,3-cycloalkanediones Научная публикация
| Журнал |
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230 |
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| Вых. Данные | Год: 1971, Том: 20, Номер: 2, Страницы: 305-309 Страниц : 5 DOI: 10.1007/bf00869030 | ||
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| Организации |
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Реферат:
1. The reaction of the silver salts of 2-acetyl-1,3-cyclohexanediones with methyl iodide in a nonpolar solvent gives 3-methoxy-2-acetyl-2-cyclohexen-1-ones (main product) and 2-methyl-2-acetyl-1,3-cyclo-hexanediones. 2. 2-Acetyl-1,3-cyclopentanedione under the same conditions forms only the corresponding 1(3)-O-methyl ether in approximately 15% yield. 3. The data of the IR spectra for 3-methoxy-2-acetyl-2-cyclopenten-1-one testify that the side acetyl group is not coplanar with the cyclic multiple bonds.
Библиографическая ссылка:
Akhrem A.A.
, Moiseenkov A.M.
, Lakhvich F.A.
, Poselenov A.I.
, Ivanova T.M.
O- and C-methylation of some 2-acetyl-1,3-cycloalkanediones
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1971. V.20. N2. P.305-309. DOI: 10.1007/bf00869030 OpenAlex
O- and C-methylation of some 2-acetyl-1,3-cycloalkanediones
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1971. V.20. N2. P.305-309. DOI: 10.1007/bf00869030 OpenAlex
Идентификаторы БД:
| OpenAlex: | W2009140340 |
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