Hydrocarbomethoxylation of 1-hexene with formic acid and methanol under conditions of phosphoric acid catalysis

Hydrocarbomethoxylation of 1-hexene with formic acid and methanol under conditions of phosphoric acid catalysis Full article

Journal

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230

Output data

Year: 1971, Volume: 20, Number: 5, Pages: 1034-1036 Pages count : 3 DOI: 10.1007/bf00862225

Authors

Ordyan M.B. ¹ , Grigoryan V.S. ¹ , Avetisyan R.V. ¹ , Éidus Ya.T. ¹

Affiliations

1	D. N. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

When the hydrocarbomethoxylation of 1-hexene with formic acid is run at atmospheric pressure and temperatures close to room temperature, in the presence of conc. H3PO4, an increase in the relative amount of the latter, as well as an increase in the reaction temperature in the investigated range, both favor an increase in the yields of the methyl esters of the C7 acids, in particular, those containing two methyl groups on the quaternary carbon atom in the α-position. An increase in the relative amount of formic acid also favors an increase in the amounts of these esters in the obtained mixtures of esters.

Ordyan M.B. , Grigoryan V.S. , Avetisyan R.V. , Éidus Y.T.
Hydrocarbomethoxylation of 1-hexene with formic acid and methanol under conditions of phosphoric acid catalysis
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1971. V.20. N5. P.1034-1036. DOI: 10.1007/bf00862225 OpenAlex

OpenAlex:

W2076556996

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