Novel (1H-tetrazol-5-yl-NNO-azoxy)furazans and their energetic salts: synthesis, characterization and energetic properties

Novel (1H-tetrazol-5-yl-NNO-azoxy)furazans and their energetic salts: synthesis, characterization and energetic properties Full article

Journal

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Output data

Year: 2022, Volume: 32, Number: 6, Pages: 714-716 Pages count : 3 DOI: 10.1016/j.mencom.2022.11.002

Authors

Leonov Nikita E. ¹ , Emel'yanov Artem E. ^2,1 , Klenov Michael S. ¹ , Churakov Aleksandr M. ¹ , Strelenko Yurii A. ¹ , Pivkina Alla N. ³ , Fedyanin Ivan V. ^4,5 , Lempert David B. ⁶ , Kon'kova Tatiana S. ³ , Matyushin Yurii N. ³ , Tartakovsky Vladimir A. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation
2	Department of Chemistry, M. V. Lomonosov Moscow State University, 119991 Moscow, Russian Federation
3	N. N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, 119991 Moscow, Russian Federation
4	A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991 Moscow, Russian Federation
5	G. V. Plekhanov Russian University of Economics, 117997 Moscow, Russian Federation
6	Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, 142432 Chernogolovka, Moscow Region, Russian Federation

Six novel energetic furazans containing tetrazol-5-yl-NNO-azoxy moiety were synthesized using (cyano-NNO-azoxy)-furazans as starting compounds. The obtained compounds exhibit high enthalpies of formation (531–792 kcal kg–1), acceptable densities (1.70–1.76 g cm–3), good thermal stability (Tonset = 146–199 °C), and, as a result, excellent detonation performance (detonation velocities of 8.61–8.95 km s−1 and detonation pressures of 31.6–36.0 GPa).

Leonov N.E. , Emel'yanov A.E. , Klenov M.S. , Churakov A.M. , Strelenko Y.A. , Pivkina A.N. , Fedyanin I.V. , Lempert D.B. , Kon'kova T.S. , Matyushin Y.N. , Tartakovsky V.A.
Novel (1H-tetrazol-5-yl-NNO-azoxy)furazans and their energetic salts: synthesis, characterization and energetic properties
Mendeleev Communications. 2022. V.32. N6. P.714-716. DOI: 10.1016/j.mencom.2022.11.002 WOS Scopus OpenAlex

≡ Web of science:	WOS:000892210700002
≡ Scopus:	2-s2.0-85145856205
≡ OpenAlex:	W4310106096