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Hydrogen generation by gasification of phenol and alcohols in supercritical water Научная публикация

Журнал International Journal of Hydrogen Energy
ISSN: 0360-3199 , E-ISSN: 1879-3487
Вых. Данные Год: 2020, Том: 45, Номер: 55, Страницы: 30178-30187 Страниц : 10 DOI: 10.1016/j.ijhydene.2020.08.086
Авторы Bogdan Viktor I. 1,2 , Koklin Aleksey E. 2 , Bogdan Tatiana V. 1,2 , Mishanin Igor I. 2 , Kalenchuk Alexander N. 1,2 , Laptinskaya Tatiana V. 3 , Kustov Leonid M. 1,2
Организации
1 Lomonosov Moscow State University, Department of Chemistry, 3 Leninskie Gory, 119991, Moscow, Russian Federation
2 N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Prosp., 119991, Moscow, Russian Federation
3 Lomonosov Moscow State University, Department of Physics, 2 Leninskie Gory, 119991, Moscow, Russian Federation

Реферат: The conversion of phenol, cyclohexanol (a hydrogenated analog of phenol for comparison with phenol), and ethanol into gas products in supercritical water (SCW) was studied with the goal to compare the reactivity of their aqueous solutions with the structural features obtained by the method of classical molecular dynamics. Transformation of phenol and alcohols occurs in different ways. In the case of alcohols, the conversion of 75–100% is achieved at 600 °C with noticeable gasification. At the same time, the conversion of phenol is only 47% and no gas products are formed at all. The complete conversion of phenol is achieved at a temperature of 750 °C, while the degree of gasification does not exceed 30%. It is shown that an increase in the phenol gasification degree is possible by pre-catalytic hydrogenation of phenol into cyclohexanol.
Библиографическая ссылка: Bogdan V.I. , Koklin A.E. , Bogdan T.V. , Mishanin I.I. , Kalenchuk A.N. , Laptinskaya T.V. , Kustov L.M.
Hydrogen generation by gasification of phenol and alcohols in supercritical water
International Journal of Hydrogen Energy. 2020. V.45. N55. P.30178-30187. DOI: 10.1016/j.ijhydene.2020.08.086 WOS Scopus OpenAlex
Идентификаторы БД:
Web of science: WOS:000582322100021
Scopus: 2-s2.0-85090700937
OpenAlex: W3084503195
Цитирование в БД:
БД Цитирований
OpenAlex 15
Scopus 14
Web of science 12
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