Synthesis of Acyclic Geminal Bis-peroxides

Synthesis of Acyclic Geminal Bis-peroxides Review

Journal

Russian Journal of Organic Chemistry
ISSN: 1608-3393 , E-ISSN: 1070-4280

Output data

Year: 2021, Volume: 57, Number: 6, Pages: 853-878 Pages count : 26 DOI: 10.1134/s1070428021060014

Authors

Bityukov O.V. ¹ , Vil V.A. ¹ , Terent’ev A.O. ¹

Affiliations

1	Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 142432, Moscow, Russia

The review covers the state of the art in methods of synthesis of acyclic geminal bis-peroxides, including bis-hydroperoxides, bis(1-hydroperoxyalkyl) peroxides, and 1-hydroperoxyalkyl 1-hydroxyalkyl peroxides. Most attention has been paid to the literature since 2000. This period of time is characterized by studies of mechanisms of formation of peroxides and hence by the development of effective and scalable procedures for the synthesis of acyclic geminal bis-peroxides via reactions of carbonyl compounds, ketals, and enol ethers with hydrogen peroxide and hydroperoxides in media that are uncommon for this field of chemistry. These procedures made it possible to extend the scope of application of acyclic geminal bis-peroxides in materials chemistry as initiators of radical polymerization and cross-linking.

Bityukov O.V. , Vil V.A. , Terent’ev A.O.
Synthesis of Acyclic Geminal Bis-peroxides
Russian Journal of Organic Chemistry. 2021. V.57. N6. P.853-878. DOI: 10.1134/s1070428021060014 WOS Scopus OpenAlex

≡ Web of science:	WOS:000675572400001
≡ Scopus:	2-s2.0-85111880579
≡ OpenAlex:	W3186829561