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Significant impact of 3-positioned substituent on the fluorescent properties of 5-hydroxyisoquinolones Full article

Journal Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436
Output data Year: 2025, Volume: 35, Number: 2, Pages: 179-182 Pages count : 4 DOI: 10.71267/mencom.7618
Authors Belyy Alexander Yu 1 , Sokolova Alena D 1 , Salikov Rinat Faritovich 1 , Trainov Konstantin P 1 , Platonov Dmitry Nikolaevich 1 , Tomilov Yury Vasil'evich 1
Affiliations
1 N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation

Abstract: Fluorescent properties of 5-hydroxyisoquinolone-3,4,6,7,8- pentacarboxylates and their 4,6,7,8-tetracarboxylate analogs lacking a 3-positioned electron-withdrawing ester group differ substantially. The presence of an electron-withdrawing group at position 3 in the 5-hydroxyisoquinolone system was found crucial for their vibrational relaxation in the anionic forms, which highlights the importance of substitution pattern providing valuable insights for future research in this area.
Cite: Belyy A.Y. , Sokolova A.D. , Salikov R.F. , Trainov K.P. , Platonov D.N. , Tomilov Y.V.
Significant impact of 3-positioned substituent on the fluorescent properties of 5-hydroxyisoquinolones
Mendeleev Communications. 2025. V.35. N2. P.179-182. DOI: 10.71267/mencom.7618 WOS Scopus OpenAlex
Identifiers:
≡ Web of science: WOS:001506165900001
≡ Scopus: 2-s2.0-105007475782
≡ OpenAlex: W4407709864
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