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Influence of the anion ratio in the composition of mixed benzoate/pentafluorobenzoate complexes of europium on the structure and photoluminescent properties Научная публикация

Журнал Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436
Вых. Данные Год: 2025, Том: 35, Номер: 1, Страницы: 35-38 Страниц : 4 DOI: 10.71267/mencom.7566
Авторы Shmelev Maxim A. 1 , Levina Anastasia A. 2 , Chistyakov Aleksandr S. 1 , Varaksina Evgeniya A. 3 , Voronina Julia K. 1 , Razgonyaeva Galina A. 1 , Taidakov Il'ya Viktorovich 3 , Sidorov Alexey A. 1 , Eremenko Igor Leonidovich 1
Организации
1 N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation
2 N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation
3 P. N. Lebedev Physical Institute, Russian Academy of Sciences, 119991 Moscow, Russian Federation

Реферат: Mixed carboxylate benzoate (bz)/pentafluorobenzoate (pfb) complexes with different ratios of pfb and bz anions in the {Eu(EtOH)2(pfb)(bz)2}n and {Eu(EtOH)(pfb)2(bz)}n compositions were obtained and structurally characterized. Changes in the pfb/bz ratio lead to changes in the geometry of the polymer chains and the lanthanide polyhedron, as well as to a rearrangement of the system of non-covalent interactions, which also affects the photoluminescent properties. The synthesized compounds were characterized by X-ray diffraction study, IR spectroscopy and CHN analysis; non-covalent interactions were analyzed using Hirshfeld surface analysis.
Библиографическая ссылка: Shmelev M.A. , Levina A.A. , Chistyakov A.S. , Varaksina E.A. , Voronina J.K. , Razgonyaeva G.A. , Taidakov I.V. , Sidorov A.A. , Eremenko I.L.
Influence of the anion ratio in the composition of mixed benzoate/pentafluorobenzoate complexes of europium on the structure and photoluminescent properties
Mendeleev Communications. 2025. V.35. N1. P.35-38. DOI: 10.71267/mencom.7566 OpenAlex
Идентификаторы БД:
OpenAlex: W4406798423
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