Electrosynthesis of N-unsubstituted enaminosulfones from vinyl azides and sodium sulfinates mediated by NH4I Научная публикация
| Журнал |
Tetrahedron Letters
ISSN: 0040-4039 , E-ISSN: 1873-3581 |
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| Вых. Данные | Год: 2021, Том: 84, Номер статьи : 153436, Страниц : DOI: 10.1016/j.tetlet.2021.153436 | ||
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Реферат:
A wide range of N-unsubstituted enaminosulfones were obtained via electrochemical sulfonylation of vinyl azides with sulfonyl radicals generated from sodium sulfinates. The discovery of N-unsubstituted enaminosulfones synthesis is based on a unique ability of the azido group to eliminate the N2 molecule. The process is performed under constant current conditions in an experimentally convenient undivided electrochemical cell equipped with a graphite anode and a stainless steel cathode applying NH4I both as the redox catalyst and the supporting electrolyte.
Библиографическая ссылка:
Mulina O.M.
, Doronin M.M.
, Terent'ev A.O.
Electrosynthesis of N-unsubstituted enaminosulfones from vinyl azides and sodium sulfinates mediated by NH4I
Tetrahedron Letters. 2021. V.84. 153436 . DOI: 10.1016/j.tetlet.2021.153436 WOS Scopus OpenAlex
Electrosynthesis of N-unsubstituted enaminosulfones from vinyl azides and sodium sulfinates mediated by NH4I
Tetrahedron Letters. 2021. V.84. 153436 . DOI: 10.1016/j.tetlet.2021.153436 WOS Scopus OpenAlex
Идентификаторы БД:
| Web of science: | WOS:000715850500006 |
| Scopus: | 2-s2.0-85116871058 |
| OpenAlex: | W3203581723 |