Silver Instead of Gold in Nitronyl Nitroxide Chemistry

Silver Instead of Gold in Nitronyl Nitroxide Chemistry Full article

Journal

Organometallics
ISSN: 1520-6041 , E-ISSN: 0276-7333

Output data

Year: 2025, Volume: 44, Number: 7, Pages: 892–898 Pages count : DOI: 10.1021/acs.organomet.5c00042

Authors

Zayakin Igor A. ¹ , Romanenko Galina V. ² , Korlyukov Alexander A. ³ , Tretyakov Evgeny V. ¹

Affiliations

1	N.D. Zelinsky Institute of Organic Chemistry, Leninsky Avenue 47, Moscow 119991, Russian Federation
2	International Tomography Center, Institutskaya Str. 3a, Novosibirsk 630090, Russian Federation
3	A.N. Nesmeyanov Institute of Organoelement Compounds, Vavilov Str. 28, Moscow 119991, Russian Federation

A nitronyl nitroxide organosilver derivative─an accessible and effective partner for cross-coupling of aryl- and heteroaryl halides─is reported for the first time. The novel cross-coupling method is based on preparation of an organosilver reagent containing a bulky N-heterocyclic carbene ligand, namely, SIPrAgNN, and a catalytic system consisting of Pd2dba3·CHCl3 and phosphine ligand MeCgPPh having an adamantane-like framework. The newly developed protocol was found to be well-compatible with various aryl- and heteroaryl halides, thus expanding the scope of directed synthesis of functionalized nitronyl nitroxide radicals and high-spin molecules.

Zayakin I.A. , Romanenko G.V. , Korlyukov A.A. , Tretyakov E.V.
Silver Instead of Gold in Nitronyl Nitroxide Chemistry
Organometallics. 2025. V.44. N7. P.892–898. DOI: 10.1021/acs.organomet.5c00042 WOS OpenAlex

Web of science:	WOS:001448101500001
OpenAlex:	W4408477757

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