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Energetic [1,2,5]oxadiazolo [2,3-a]pyrimidin-8-ium Perchlorates: Synthesis and Characterization Научная публикация

Журнал Molecules
ISSN: 1420-3049
Вых. Данные Год: 2022, Том: 27, Номер: 23, Номер статьи : 8443, Страниц : DOI: 10.3390/molecules27238443
Авторы Strizhenko Kirill V. 1 , Smirnova Anastasia D. 2,1 , Filatov Sergei A. 2 , Sinditskii Valery P. 2,1 , Stash Adam I. 3 , Suponitsky Kyrill Yu. 3 , Monogarov Konstantin A. 4 , Kiselev Vitaly G. 5 , Sheremetev Aleksei B. 1
Организации
1 Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russia
2 Mendeleev University of Chemical Technology, 125047 Moscow, Russia
3 Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119334 Moscow, Russia
4 Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, 119991 Moscow, Russia
5 Institute of Chemical Kinetics and Combustion, Russian Academy of Sciences, Siberian Branch, 630090 Novosibirsk, Russia

Реферат: A convenient method to access the above perchlorates has been developed, based on the cyclocondensation of 3-aminofurazans with 1,3-diketones in the presence of HClO4. All compounds were fully characterized by multinuclear NMR spectroscopy and X-ray crystal structure determinations. Initial safety testing (impact and friction sensitivity) and thermal stability measurements (DSC/DTA) were also carried out. Energetic performance was calculated by using the PILEM code based on calculated enthalpies of formation and experimental densities at r.t. These salts exhibit excellent burn rates and combustion behavior and are promising ingredients for energetic materials.
Библиографическая ссылка: Strizhenko K.V. , Smirnova A.D. , Filatov S.A. , Sinditskii V.P. , Stash A.I. , Suponitsky K.Y. , Monogarov K.A. , Kiselev V.G. , Sheremetev A.B.
Energetic [1,2,5]oxadiazolo [2,3-a]pyrimidin-8-ium Perchlorates: Synthesis and Characterization
Molecules. 2022. V.27. N23. 8443 . DOI: 10.3390/molecules27238443 WOS Scopus OpenAlex
Идентификаторы БД:
≡ Web of science: WOS:000897131300001
≡ Scopus: 2-s2.0-85143628081
≡ OpenAlex: W4311530280
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