Catalytic reduction of carbonyl- and hydroxy- containing furan compounds

Catalytic reduction of carbonyl- and hydroxy- containing furan compounds Full article

Journal

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230

Output data

Year: 1964, Volume: 13, Number: 3, Pages: 496-498 Pages count : 3 DOI: 10.1007/bf00844168

Authors

Shuikin N.I. ¹ , Bel'skii I.F. ¹ , Savekina O.N. ¹

Affiliations

1	N. D Zelinskii Institute of Organic Chemistry, Academy of Sciences, USSR

1. 2-Acylfuran homologs were reduced in yields of up to 95% to the corresponding furan homologs by hydrogenation by the flow method over skeletal Cu-Al at 220°. In this way we prepared: 2-methyl-5-propylfuran, 2-ethyl-3,5-dimethylfuran, and 2,3-diethyl-5-methylfuran. 2. On hydrogenation over Pt-C or skeletal Ni-Al by the flow method at 220°α-alkylfurfuryl alcohols are first reduced to the corresponding 2-alkylfurans, and the latter then suffer hydrogenolysis at the C-O bond over Pt-C and conjugated hydrogenolysis over skeletal Ni-Al with formation of aliphatic ketones.

Shuikin N.I. , Bel'skii I.F. , Savekina O.N.
Catalytic reduction of carbonyl- and hydroxy- containing furan compounds
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1964. V.13. N3. P.496-498. DOI: 10.1007/bf00844168 OpenAlex

OpenAlex:

W1970117936

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