Stereochemistry of cyclic compounds. Communication 61. Structural and steric orientation in the diene condensations of some vinylcycloalkenes with unsymmetrical trans dienophiles

Stereochemistry of cyclic compounds. Communication 61. Structural and steric orientation in the diene condensations of some vinylcycloalkenes with unsymmetrical trans dienophiles Full article

Journal

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230

Output data

Year: 1964, Volume: 13, Number: 8, Pages: 1368-1373 Pages count : 6 DOI: 10.1007/bf00850336

Authors

Segal' G.M. ¹ , Rybkina L.P. ¹ , Kucherov V.F. ¹

Affiliations

1	N. D Zelinskii Institute of Organic Chemistry, Academy of Sciences, USSR

1. The diene condensation of 1-(1-chlorovinyl)cyclohexene (IV) with trans-3-(chloroformyl)acrylic esters and with methyl trans-3-nitroacrylate goes structurally and sterically selectively with formation of trans-syn adducts with the more electronegative group in the ortho position. 2. The condensation of methyl trans-3-nitroacrylate with 1-vinylcyclohexene (I) was studied, and the structure and configurations of the isomeric adducts formed were proved.

Segal' G.M. , Rybkina L.P. , Kucherov V.F.
Stereochemistry of cyclic compounds. Communication 61. Structural and steric orientation in the diene condensations of some vinylcycloalkenes with unsymmetrical trans dienophiles
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1964. V.13. N8. P.1368-1373. DOI: 10.1007/bf00850336 OpenAlex

OpenAlex:

W1981863065

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